Fabrication of cellulose acetate‐based radiation grafted anion exchange membranes for fuel cell application

• Published in: Journal of applied polymer science Vol. 138; no. 10
• Main Authors: Samaniego, Angelo Jacob, Arabelo, Allison Kaye, Sarker, Mrittunjoy, Mojica, Felipe, Madrid, Jordan, Chuang, Po‐Ya Abel, Ocon, Joey, Espiritu, Richard
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 10.03.2021; Wiley Subscription Services, Inc
• Subjects: Acetylation; Anion exchanging; batteries and fuel cells; Cellulose acetate; cellulose and other wood products; Fuel cells; Functional groups; Gamma rays; Grafting; Ion currents; Ion exchange; Ions; irradiation; Materials science; Membranes; Operating temperature; Parameters; Polymers; Radiation dosage; Thermogravimetric analysis
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.49947

Novel cellulose acetate‐based anion exchange membranes (CA‐AEM) are successfully synthesized via gamma radiation grafting as a possible renewable alternative to commercial AEMs. Using CA film precursors with degree of acetylation of 2.5, the synthesized AEM shows a high ion exchange capacity of 2.15 mmol g−1 obtained at high degree of grafting of 45%. It was determined using thermogravimetric analysis that the radiation‐grafted CA‐AEM has stable amine functional groups under oxygen environment within the normal operating temperature range of alkaline fuel cells. The CA‐AEM also exhibits appreciable performance over a range of temperatures, with a highest ionic conductivity of up to 0.163 S cm−1 depending on the synthesis parameters. Results revealed that membranes prepared using gamma radiation dose of 31 kGy and above are susceptible to mechanical and dimensional instability due to increased water uptake and degree of swelling. Further study should consider the balance between grafting parameters and the desired hydrophysical properties.