Preparation of Al(C 6F 5) 3 and its use for the modification of methylalumoxane

• Published in: Journal of molecular catalysis. A, Chemical Vol. 132; no. 2; pp. 231 - 239
• Main Authors: Lee, Choong Hoon, Lee, Sang Jin, Park, Joon Won, Kim, Kyong Hee, Lee, Bun Yeol, Oh, Jae Seung
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.06.1998; Elsevier
• Subjects: Al(C 6F 5) 3; Applied sciences; B(C 6F 5) 3; Exact sciences and technology; Lewis acidity; Methylalumoxane (MAO); Olefin polymerization; Organic polymers; Physicochemistry of polymers; Polymerization; Preparation, kinetics, thermodynamics, mechanism and catalysts; Lewis acidity; B(C 6F 5) 3; Olefin polymerization; Al(C 6F 5) 3; Methylalumoxane (MAO); Polyethylene; Propylene polymer; Metathesis; Olefin polymer; Composition effect; Aluminium Organic compounds; Complex catalyst polymerization; Experimental study; Catalyst activity
• ISSN: 1381-1169; 1873-314X
• DOI: 10.1016/S1381-1169(97)00277-X

Tris(pentafluorophenyl)aluminum was prepared from a metathesis between AlMe 3 and B(C 6F 5) 3 in a quantitative yield. Out of CN stretching frequency of various benzonitrile adducts, it is found that the title aluminum compound is a quite weaker Lewis acid than B(C 6F 5) 3 is, and has rather similar acidity as AlMe 3. When mixtures of methylalumoxane (MAO) and Al(C 6F 5) 3·(toluene) 0.5 or B(C 6F 5) 3 were heated at 65°C, it is observed that the C 6F 5 group was exchanged with the methyl group of the MAO. Several MAOs were prepared with variable degrees of modification. Catalytic activity of pristine MAO and modified MAOs were tested for ethylene and propylene polymerization. It is found that the activity is enhanced with the modification, and the effectiveness is reduced as modification level is increased. In particular, 7-fold increase of activity for polyethylene is observed, when 5.5×10 −3 equimolar amount of Al(C 6F 5) 3·(toluene) 0.5 is used for the modification. The modification with B(C 6F 5) 3 incorporates boron atoms into the oligomeric chain, and is less effective than that with the aluminum analogue.