Nd3+ high order electrical susceptibility induced by CdS nanocrystals in a phosphate glass matrix

• Published in: Journal of non-crystalline solids Vol. 612; p. 122345
• Main Authors: Camilo, Nilmar S., Filho, José C.S., Pilla, V., Messias, D.N., Silva, Aniele C.A., Dantas, Noelio O., Andrade, Acácio A.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.07.2023
• Subjects: CdS nanocrystals; Nd3+ ions; Nonlinear optical properties; Nonlinear refractive index; Phosphate glass; Third and fifth nonlinearity; Time-resolved z-scan; Nonlinear optical properties; Time-resolved z-scan; Third and fifth nonlinearity; Phosphate glass; CdS nanocrystals; Nd3+ ions; Nonlinear refractive index
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2023.122345

•Discrimination between thermal and populations effects.•Nonlinear optical properties of Nd/CdS phosphate glass matrix.•Third and fifth order optical nonlinearity.•Energy transfer between nd and CdS nanocrystals. In this work the nonlinear optical properties of a phosphate glass matrix doped with Nd3+and codoped with CdS nanocrystals have been investigated by the time-resolved Z-scan technique. Analyzing the transient signal, it was possible to discriminate the thermal effect from the populational effects on the nonlinear refraction and absorption, allowing the determination of the parameters n2’, n2” and n4’. The dependence of these parameters on the relative concentration of Nd and CdS was also investigated, and a linear increase of these parameters with the CdS absorption was observed. Evidence of energy transfer between Nd and CdS nanocrystals was investigated by the determination of the non-radiative decay rate through lifetime measurements monitoring the emission at 1064 nm referring to the transition 4F3/2⟶ 4I11/2 of the Nd3+.