A simultaneous analysis of ν5, ν6, and the ground state of deuterated hydrazoic acid
A simultaneous analysis of ν 4, ν 5, ν 6, and the ground state of DN 3 has been performed based on data from microwave, far-infrared, infrared, and Raman gas-phase spectra. The analysis takes into account resonance between the ground state and ν 5 due to centrifugal distortion, a- and b-Coriolis res...
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Published in | Journal of molecular spectroscopy Vol. 128; no. 2; pp. 309 - 320 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
San Diego, CA
Elsevier Inc
1988
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | A simultaneous analysis of
ν
4,
ν
5,
ν
6, and the ground state of DN
3 has been performed based on data from microwave, far-infrared, infrared, and Raman gas-phase spectra. The analysis takes into account resonance between the ground state and
ν
5 due to centrifugal distortion,
a- and
b-Coriolis resonances between
ν
5 and
ν
6, and
a-Coriolis resonance between
ν
6 and
ν
4.
A set of spectroscopic constants for all four levels and a number of interaction parameters have been obtained. The following values for the ground state rotational constants have been obtained:
A
0 = 11.499517(3) cm
−1,
B
0 = 0.3786230(7) cm
−1,
C
0 = 0.3657530(7) cm
−1. |
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ISSN: | 0022-2852 1096-083X |
DOI: | 10.1016/0022-2852(88)90149-X |