Zr-MOF/MXene composite for enhanced photothermal catalytic CO2 reduction in atmospheric and industrial flue gas streams

• Published in: Carbon Capture Science & Technology Vol. 13; p. 100274
• Main Authors: Meng, Yang, Yue, Feng, Zhang, Shuo, Zhang, Lingji, Li, Cong, Shi, Mengke, Ma, Yongpeng, Berrettoni, Mario, Zhang, Xiaojing, Zhang, Hongzhong
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.12.2024; Elsevier
• Subjects: Atmosphere; CO2 reduction; Industrial emissions; Photothermal catalytic; Zr-MOF/MXene; Zr-MOF/MXene; CO2 reduction; Industrial emissions; Photothermal catalytic; Atmosphere
• ISSN: 2772-6568; 2772-6568
• DOI: 10.1016/j.ccst.2024.100274

In this study, a novel composite was engineered by integrating Zr-MOF (NH2-UIO-66) with MXene layers through electrostatic self-assembly. Under simulated sunlight and at 80 °C, this composite material achieved nearly complete conversion of low-concentration atmospheric CO2 to CO and CH4 without additional sacrificial agents or alkaline absorption liquids, marking one of the few reports demonstrating near-complete reduction of low-concentration CO2 directly from the air. For high-concentration CO2 in industrial flue gas, the composite utilized residual heat at 80 °C without additional energy input, exhibiting excellent CO2 reduction efficiency with CO and CH4 production rates of 127 μmol·g-1·h-1 and 330 μmol·g-1·h-1, respectively, resulting in a total production rate 4.76 times higher than that in the air. Compared to most reports on thermocatalytic CO2 reduction (>300 °C), this material shows significant advantages below 100 °C. The performance improvement is attributed to the introduction of Zr-MOF, which provides additional active sites and reduces activation energy. Additionally, the localized surface plasmon resonance (LSPR) effect of MXene facilitates the migration of thermal charge carriers to Zr4+ sites within the MOF. Density Functional Theory (DFT) calculations validate these findings. Overall, Zr-MOF/MXene composite holds potential for reducing CO2 in air and industrial settings, advancing energy conversion and environmental management.