Feasibility of green mechanochemical synthesis for dual function materials preparation

• Published in: Journal of CO2 utilization Vol. 86; p. 102895
• Main Authors: Danielis, Maila, Merkouri, Loukia-Pantzechroula, Braga, Andrea, Trovarelli, Alessandro, Duyar, Melis S., Colussi, Sara
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.08.2024; Elsevier
• Subjects: CO2 capture and utilization; Direct air capture; Dry milling; Dual function materials; Mechanochemical synthesis; Reverse water-gas shift; CO2 capture and utilization; Reverse water-gas shift; Direct air capture; Dry milling; Dual function materials; Mechanochemical synthesis
• ISSN: 2212-9820; 2212-9839
• DOI: 10.1016/j.jcou.2024.102895

Dual function materials (DFMs) are key for the integrated capture of CO2 from waste gas streams and its valorisation to valuable chemicals, such as syngas. To be able to function in commercial applications, DFMs require both high capture capacity and catalytic activity, achieved by optimising the synergistic interactions among the catalytic metals, support and adsorbent components. To obtain increased interaction, the dry milling process can be used as a sustainable, solvent free, green synthesis method. In this work, we report the performance of RuNi bimetallic DFMs supported on CeO2-Al2O3 and promoted with CaO and Na2O, synthesised by a mild-energy mechanochemical process. The materials show generally comparable, and sometimes superior, capture capacity and increased activity in Reverse Water-Gas Shift (RWGS) reaction for CO production at 650 °C compared to their counterpart prepared by a conventional impregnation method, underlining the potential of the synthesis method for highly functional DFMs. Remarkably, high activity and stability are also maintained when O2 is present in the capture step, indicating potential for real exhaust-gases capture applications. Also, direct air capture of CO2 is reported, further underlining the benefits of the dry milling approach for creating versatile DFMs. •Successful preparation of dual function materials (DFMs) by dry milling.•Higher RWGS activity (CO production) than conventional counterparts.•Yet also chemical looping activity due to highly active RuNi particles.•O2 presence in CO2 capture feed mitigates chemical looping without affecting RWGS.•RuNi-free CaO/CeO2-Al2O3 also highly performing in capture-RWGS applications.