Tris[N‐(3‐chloro­phen­yl)pyridine‐2‐carboxamidato‐κ2N,N′]cobalt(III) monohydrate

The title complex, [Co(C12H8ClN2O)3]·H2O, has been synthesized for the first time. The complex comprises three bidentate ligands containing the pyridine‐2‐carboxamide nucleus. The distorted octa­hedral coordination around the Co atom is formed via the pyridine N atom and the deprotonated amide N ato...

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Published inActa crystallographica. Section E, Structure reports online Vol. 61; no. 11; pp. m2362 - m2364
Main Authors Yang, Qi Yun, Yang, Da Wu, Zhou, Zhong Yuan, Qi, Jian Ying, Chan, Albert S. C.
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Munksgaard International Publishers 01.11.2005
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Summary:The title complex, [Co(C12H8ClN2O)3]·H2O, has been synthesized for the first time. The complex comprises three bidentate ligands containing the pyridine‐2‐carboxamide nucleus. The distorted octa­hedral coordination around the Co atom is formed via the pyridine N atom and the deprotonated amide N atom of each ligand. One inter­molecular hydrogen bond forms between a carbonyl O atom of one ligand and the single water mol­ecule.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536805030953