Palladium-catalysed asymmetric allylic alkylation in the presence of a chiral 'light fluorous' phosphine ligand

The easily accessible, enantiopure (R)-(+)-2-diarylphosphino-2'-alkoxy-1,1'-binaphthyl 1 bearing three fluorous ponytails is an efficient ligand in the palladium-catalysed asymmetric allylic substitution of 1,3-diphenylprop-2-enyl acetate affording chiral products of up to 87% ee.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 13; pp. 1220 - 1221
Main Authors Cavazzini, M, Pozzi, G, Quici, S, Maillard, D, Sinou, D
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2001
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
HYDROGENATION
SOLVENTS
STRATEGY
COMPLEXES
SUPERCRITICAL CARBON-DIOXIDE
SEPARATION
HYDROFORMYLATION
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Summary:The easily accessible, enantiopure (R)-(+)-2-diarylphosphino-2'-alkoxy-1,1'-binaphthyl 1 bearing three fluorous ponytails is an efficient ligand in the palladium-catalysed asymmetric allylic substitution of 1,3-diphenylprop-2-enyl acetate affording chiral products of up to 87% ee.
ISSN:1359-7345
1364-548X
DOI:10.1039/b103074b