Hydrogels comprising oxidized carboxymethyl cellulose and water-soluble chitosan at varied oxidation levels: Synthesis, characterization, and adsorptive toward methylene blue

• Published in: International journal of biological macromolecules Vol. 277; no. Pt 2; p. 134351
• Main Authors: Zhang, Linyu, Li, Qianqi, Liang, Yingqi, Zhang, Guoguang, Zou, Jinmei, Fei, Peng, Lai, Wenqiang
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.10.2024
• Subjects: Adsorption; Oxidized carboxymethyl cellulose; Water-soluble chitosan; Adsorption; Oxidized carboxymethyl cellulose; Water-soluble chitosan
• ISSN: 0141-8130; 1879-0003; 1879-0003
• DOI: 10.1016/j.ijbiomac.2024.134351

Chitosan, as a biomaterial, has increasingly garnered attention. However, its limited solubility in water—only dissolving in certain dilute acidic solutions—substantially restricts its broader application. In this investigation, chitosan underwent a solubilization modification to acquire water solubility, facilitating its dissolution in neutral aqueous mediums. Subsequently, this water-soluble chitosan (WSC) was interlinked with oxidized carboxymethyl cellulose (OCMC), characterized by varied oxidation extents, to synthesize hydrogels. Structural characterization verified the formation of imine bonds resulting from crosslinking interactions between the amino groups of water-soluble chitosan and the aldehyde groups of oxidized carboxymethyl cellulose. Employing performance characterization analysis, it was discerned that an increase in the oxidation level of the oxidized carboxymethyl cellulose corresponded to a denser hydrogel network architecture and the hardness increased from 3.01 N to 6.16 N. Moreover, the capacity of these hydrogels to adsorb methylene blue was meticulously examined. Notably, the hydrogel denoted as WSC/66%OCMC manifested an adsorption capability of 28.08 mg/g for methylene blue. Analytical findings from adsorption kinetics and isotherm studies indicate that the adsorption mechanism of the WSC/66%OCMC hydrogel follows the pseudo-second-order kinetic model and corresponds to the Freundlich isotherm model. [Display omitted] •Water-soluble chitosan can be dissolved in neutral water medium.•Hydrogel hardness increased from 3.01 N to 6.16 N with higher oxidation levels.•The thermal stability of hydrogel was improved.•The hydrogel has a broad application prospect in the environmental field.