Synthesis of the sodium diphenylbis(cyanamido)phosphonium diylide by a new variation of the Staudinger reaction

The first example of a stabilized diaminophonium diazaylide, sodium diphenylbis(cyanamido)phosphonium diylide, has been synthesized by a new variation of the Staudinger reaction; the corresponding copper complex can be described as a discrete dimeric unit with [Ph2P(NCN)(2)](-) in both uni- and bi-d...

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 6; pp. 565 - 566
Main Authors Taillefer, M, Inguimbert, N, Jager, L, Merzweiler, K, Cristau, HJ
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.03.1999
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
TRANSITION
UNSUBSTITUTED DIPHENYLPHOSPHONIUM DIYLIDES
METALS
YLIDES
DERIVATIVES
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Summary:The first example of a stabilized diaminophonium diazaylide, sodium diphenylbis(cyanamido)phosphonium diylide, has been synthesized by a new variation of the Staudinger reaction; the corresponding copper complex can be described as a discrete dimeric unit with [Ph2P(NCN)(2)](-) in both uni- and bi-dentate modes (X-ray structure).
ISSN:1359-7345
1364-548X
DOI:10.1039/a808641i