Palladium-catalyzed selective B(3)-H arylation of o-carboranes with arylboronic acids at room temperature

A palladium-catalyzed selective B(3)-H arylation of o-carboranes at room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl-o-carboranes were obtained in good to excellent yields. This method provides a powerful synthetic route f...

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Published inChemical communications (Cambridge, England) Vol. 57; no. 13; pp. 1655 - 1658
Main Authors Yang, Ziyi, Wu, Yuanbo, Fu, Yatong, Yang, Jianxin, Lu, Jian, Lu, Ju-You
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 14.02.2021
Subjects
Aromatic compounds
Carborane
Crystallography
Palladium
Room temperature
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Summary:A palladium-catalyzed selective B(3)-H arylation of o-carboranes at room temperature has been developed using readily available arylboronic acids as the aryl source, and the corresponding 3-aryl-o-carboranes were obtained in good to excellent yields. This method provides a powerful synthetic route for constructing polysubstituted o-carborane derivatives.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc07591d