Preparation, characterisation and slow quantitative dissociation of a novel asymmetric N-unsubstituted dialkylsulfimide
(+/-)-S-Imino-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]thiepine, a novel asymmetric N-unsubstituted sulfimide, undergoes slow, quantitative NS bond cleavage in CDCl3 solution at 20 degrees C with a half-life of 20 h.
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Published in | Chemical communications (Cambridge, England) no. 2; pp. 189 - 190 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
21.01.1999
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Subjects | |
Online Access | Get full text |
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Summary: | (+/-)-S-Imino-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]thiepine, a novel asymmetric N-unsubstituted sulfimide, undergoes slow, quantitative NS bond cleavage in CDCl3 solution at 20 degrees C with a half-life of 20 h. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/a808356h |