Synthesis and structural characterisation of platinum silasesquioxane complexes

The reaction of partially condensed silasesquioxanes of the type [(R7Si7O9)-Si-1(OH)(2)(OR2)] (R-1 = c-C5H9, C-C6H11; R-2 = H, SiMe3) with either [Pt(dppe)(CO3)] or [Pt(dppe)Cl-2]/Ag2O leads to the formation of [(R7Si7O9)-Si-1(OR2)O2Pt(dppe)], crystallographically characterised for R-1 = c-C5H9; R-2...

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Published inChemical communications (Cambridge, England) no. 23; pp. 2627 - 2628
Main Authors Abbenhuis, HCL, Burrows, AD, Kooijman, H, Lutz, M, Palmer, MT, van Santen, RA, Spek, AL
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.12.1998
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
LIGANDS
MODELS
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Summary:The reaction of partially condensed silasesquioxanes of the type [(R7Si7O9)-Si-1(OH)(2)(OR2)] (R-1 = c-C5H9, C-C6H11; R-2 = H, SiMe3) with either [Pt(dppe)(CO3)] or [Pt(dppe)Cl-2]/Ag2O leads to the formation of [(R7Si7O9)-Si-1(OR2)O2Pt(dppe)], crystallographically characterised for R-1 = c-C5H9; R-2 = SiMe3, providing unprecedented routes to late transition metal silasesquioxane complexes.
ISSN:1359-7345
1364-548X
DOI:10.1039/a808130a