Complexes of podand-containing bis(dithiophosphonate) ligands with cobalt(II), nickel(II) and cadmium(II): recognition of CH2Cl2
Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C 6 H 4 )P(S)(SH)OCH 2 CH 2 ] 2 O ( H 2 L ) with Co(II), Ni(II) and Cd(II) in aqueous EtOH leads to complexes of formulae M 2 (L- S , S ′) 2 . The structural formulae of the compounds were deduced by physico-chemical...
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| Published in | Transition metal chemistry (Weinheim) Vol. 33; no. 7; pp. 921 - 924 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Dordrecht
Springer Netherlands
01.10.2008
Springer Nature B.V |
| Subjects | |
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| Abstract | Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C
6
H
4
)P(S)(SH)OCH
2
CH
2
]
2
O (
H
2
L
) with Co(II), Ni(II) and Cd(II) in aqueous EtOH leads to complexes of formulae M
2
(L-
S
,
S
′)
2
. The structural formulae of the compounds were deduced by physico-chemical and spectroscopic methods. It was established that complex
Ni
2
L
2
recognizes CH
2
Cl
2
. |
|---|---|
| AbstractList | Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C^sub 6^H^sub 4^)P(S)(SH)OCH^sub 2^CH^sub 2^]^sub 2^O (H ^sub 2^ L) with Co(II), Ni(II) and Cd(II) in aqueous EtOH leads to complexes of formulae M^sub 2^(L-S,S')^sub 2^. The structural formulae of the compounds were deduced by physico-chemical and spectroscopic methods. It was established that complex Ni ^sub 2^ L ^sub 2^ recognizes CH^sub 2^Cl^sub 2^.[PUBLICATION ABSTRACT] Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C 6 H 4 )P(S)(SH)OCH 2 CH 2 ] 2 O ( H 2 L ) with Co(II), Ni(II) and Cd(II) in aqueous EtOH leads to complexes of formulae M 2 (L- S , S ′) 2 . The structural formulae of the compounds were deduced by physico-chemical and spectroscopic methods. It was established that complex Ni 2 L 2 recognizes CH 2 Cl 2 . |
| Author | Pinus, Marina V. Gimadiev, Timur R. Gataulina, Alphia R. Safin, Damir A. |
| Author_xml | – sequence: 1 givenname: Alphia R. surname: Gataulina fullname: Gataulina, Alphia R. organization: A. M. Butlerov Chemistry Institute, Kazan State University – sequence: 2 givenname: Damir A. surname: Safin fullname: Safin, Damir A. email: damir.safin@ksu.ru organization: A. M. Butlerov Chemistry Institute, Kazan State University – sequence: 3 givenname: Timur R. surname: Gimadiev fullname: Gimadiev, Timur R. organization: A. M. Butlerov Chemistry Institute, Kazan State University – sequence: 4 givenname: Marina V. surname: Pinus fullname: Pinus, Marina V. organization: A. M. Butlerov Chemistry Institute, Kazan State University |
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| Cites_doi | 10.1021/ic800272v 10.1016/0277-5387(95)00108-5 10.1002/anie.196900891 10.1021/ic50098a034 10.1016/S0022-328X(00)00677-X 10.1016/0277-5387(95)00305-6 10.1016/j.molcata.2006.03.033 10.1016/j.ica.2005.09.061 10.1016/0584-8539(87)80229-5 10.1021/cr00026a001 10.1016/S0277-5387(99)00352-6 10.1016/S0277-5387(00)83108-3 10.1016/0277-5387(96)00081-2 10.1016/0022-0248(80)90098-6 10.1021/ic001184l |
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| Keywords | Vulcanization Potassium Salt Diethylene Glycol Dithiophosphates CCl4 |
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| Snippet | Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C
6
H
4
)P(S)(SH)OCH
2
CH
2
]
2
O (
H
2
L
) with Co(II), Ni(II) and Cd(II)... Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C^sub 6^H^sub 4^)P(S)(SH)OCH^sub 2^CH^sub 2^]^sub 2^O (H ^sub 2^ L) with... |
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| SubjectTerms | Catalysis Chemistry Chemistry and Materials Science Inorganic Chemistry Organometallic Chemistry Physical Chemistry |
| Title | Complexes of podand-containing bis(dithiophosphonate) ligands with cobalt(II), nickel(II) and cadmium(II): recognition of CH2Cl2 |
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