Complexes of podand-containing bis(dithiophosphonate) ligands with cobalt(II), nickel(II) and cadmium(II): recognition of CH2Cl2

Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C 6 H 4 )P(S)(SH)OCH 2 CH 2 ] 2 O ( H 2 L ) with Co(II), Ni(II) and Cd(II) in aqueous EtOH leads to complexes of formulae M 2 (L- S , S ′) 2 . The structural formulae of the compounds were deduced by physico-chemical...

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Published inTransition metal chemistry (Weinheim) Vol. 33; no. 7; pp. 921 - 924
Main Authors Gataulina, Alphia R., Safin, Damir A., Gimadiev, Timur R., Pinus, Marina V.
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 01.10.2008
Springer Nature B.V
Subjects
Catalysis
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Organometallic Chemistry
Physical Chemistry
Vulcanization
Potassium Salt
Diethylene Glycol
Dithiophosphates
CCl4
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Summary:Reaction of the potassium salts of podand-containing bis(dithiophosphonate)s [PhO(4-C 6 H 4 )P(S)(SH)OCH 2 CH 2 ] 2 O ( H 2 L ) with Co(II), Ni(II) and Cd(II) in aqueous EtOH leads to complexes of formulae M 2 (L- S , S ′) 2 . The structural formulae of the compounds were deduced by physico-chemical and spectroscopic methods. It was established that complex Ni 2 L 2 recognizes CH 2 Cl 2 .
ISSN:0340-4285
1572-901X
DOI:10.1007/s11243-008-9133-4