Acridine orange base as a dopant for n doping of C60 thin films

• Published in: Journal of applied physics Vol. 100; no. 2
• Main Authors: Li, Fenghong, Pfeiffer, Martin, Werner, Ansgar, Harada, Kentaro, Leo, Karl, Hayashi, Naoki, Seki, Kazuhiko, Liu, Xianjie, Dang, Xuan-Dung
• Format: Journal Article
• Language: English
• Published: 15.07.2006
• ISSN: 0021-8979; 1089-7550
• DOI: 10.1063/1.2219374

We present a study on n doping of C60 thin films by acridine orange base [3,6-bis(dimethylamino)acridine(AOB)] combining conductivity, field effect, and Seebeck measurements. An increase of more than six orders of magnitude in conductivity is observed for a doping ratio of 6mol%, accompanied by a decrease in the activation energy from 0.64to0.15eV compared to the undoped C60. We observe a clear doping effect immediately after sample preparation, but also a further activation by annealing or illumination. The field effect and Seebeck measurements confirm n-type conduction of C60 thin films and show that deep donor states are formed in AOB-doped C60 thin films. A field effect mobility of 0.2cm2∕Vs is achieved for a doping level of 1.8mol%. Near Infrared (NIR) and Fourier transform infrared (FTIR) spectra demonstrate electron transfer from the dopant to the matrix: For C60 doped with AOB, C60− is present in NIR absorption and FTIR spectra. On the other hand, a peak corresponding to acridine orange [3,6-bis(dimethylamino)acridinium chloride (AOBH+)] is also observed in the FTIR spectrum of C60:AOB, where AOBH+ corresponds to AOB with one additional proton attached. Electrochemical data of AOB and AOBH+ in acetontrile suggest that the AOB radical cation is not stable, but is rapidly transformed into a compound with similar properties to AOBH+. Conductivities of C60 thin films doped with bis(ethylenedithio)-tetrathiafulvalene were also investigated to confirm that the doping effect of AOB in C60 does not result from a simple electron transfer from AOB to C60.