Green Baeyer–Villiger oxidation with hydrogen peroxide: Sn[N(SO 2 C 8 F 17 ) 2 ] 4 as a highly selective Lewis acid catalyst in a fluorous biphase system

In a fluorous biphasic catalytic system for Baeyer-Villiger oxidation of cyclic ketones, it was shown that Sn[N(SOCF)] catalyst can give an excellent yield and selectivity with the green, safe and cheap 35% aqueous hydrogen peroxide as the oxidant. Furthermore, it was also found that the catalyst ca...

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Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 5; no. 5; pp. 524 - 528
Main Authors Hao, Xiuhua, Yamazaki, Osamu, Yoshida, Akihiro, Nishikido, Joji
Format Journal Article
LanguageEnglish
Published 01.01.2003
Subjects
Catalysis
Catalysts
Hydrogen peroxide
Ketones
Lewis acid
Oxidants
Oxidation
Selectivity
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Summary:In a fluorous biphasic catalytic system for Baeyer-Villiger oxidation of cyclic ketones, it was shown that Sn[N(SOCF)] catalyst can give an excellent yield and selectivity with the green, safe and cheap 35% aqueous hydrogen peroxide as the oxidant. Furthermore, it was also found that the catalyst can be completely recovered and reused without loss of its activity in the fluorous immobilized phase.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1463-9262
1463-9270
DOI:10.1039/B304439D