Equilibrium kinetic analysis of a model mixture of anthracene and benzothiophene

The kinetic and thermodynamic parameters of the hydrogenation of an anthracene–benzothiophene model mixture were calculated. The rate constants of forward and reverse reactions, the equilibrium constant, the activation energies, and the heat effects of hydrogenation reactions were determined by equi...

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Published inSolid fuel chemistry Vol. 49; no. 5; pp. 335 - 338
Main Authors Baikenov, M. I., Tateeva, A. B., Akhmetkarimova, Zh. S., Tusipkhan, A., Mataeva, A. Zh, Esenbaeva, K. K.
Format Journal Article
LanguageEnglish
Published New York Allerton Press 01.09.2015
Subjects
Chemistry
Chemistry and Materials Science
Physical Chemistry
Model Mixture
Anthracene
Lignite
Heat Effect
Liquefaction
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Summary:The kinetic and thermodynamic parameters of the hydrogenation of an anthracene–benzothiophene model mixture were calculated. The rate constants of forward and reverse reactions, the equilibrium constant, the activation energies, and the heat effects of hydrogenation reactions were determined by equilibrium kinetic analysis for second-order reactions in a model mixture of anthracene and benzothiophene in the presence of an iron-containing catalyst over a temperature range of 648–698 K at a pressure of 6 MPa.
ISSN:0361-5219
1934-8029
DOI:10.3103/S0361521915050031