Hybrid chlorobismuthate(III) “trapping” Br2 unit: Crystal structure and theoretical investigation of non-covalent Cl⋯Br interactions in (1-MePy)3{[Bi2Cl9](Br2)}

[Display omitted] •Polyhalide hybrids.•Bromide complexes of Bi(III)•Halogen bonding “traps” dibromine. Novel hybrid chlorobismuthate(III) with “captured” dibromine, (1-MePy)3{[Bi2Cl9](Br2)} (1), was isolated and characterized by X-ray diffractometry, thermogravimetric analysis and Raman spectroscopy...

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Published inInorganica Chimica Acta Vol. 513; p. 119932
Main Authors Usoltsev, Andrey N., Korobeynikov, Nikita A., Novikov, Alexander S., Plyusnin, Pavel E., Fedin, Vladimir P., Sokolov, Maxim N., Adonin, Sergey A.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.12.2020
Elsevier Science Ltd
Subjects
Bismuth
Crystal structure
Halide complexes
Halogen bonding
Raman spectroscopy
Supramolecular contacts
Thermogravimetric analysis
Bismuth
Halogen bonding
Halide complexes
Supramolecular contacts
Crystal structure
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Summary:[Display omitted] •Polyhalide hybrids.•Bromide complexes of Bi(III)•Halogen bonding “traps” dibromine. Novel hybrid chlorobismuthate(III) with “captured” dibromine, (1-MePy)3{[Bi2Cl9](Br2)} (1), was isolated and characterized by X-ray diffractometry, thermogravimetric analysis and Raman spectroscopy. The features of non-covalent interactions in solid state were investigated by theoretical methods.
ISSN:0020-1693
1873-3255
DOI:10.1016/j.ica.2020.119932