Pathway to a molecular calcium methyl

The dimeric β-diketiminato calcium hydride, [(BDI)CaH] (BDI = HC{(Me)CN-2,6- Pr C H } ), reacts with ZnMe to afford the bimetallic calcium zincate complex, [(BDI)Ca(μ-CH ) Zn(μ-H)] , which subsequently undergoes an intramolecular reaction to effect the formation of [(BDI)CaMe] , a notable omission f...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 60; no. 61; pp. 7882 - 7885
Main Authors Pearce, Kyle G, Neale, Samuel E, McMullin, Claire L, Mahon, Mary F, Hill, Michael S
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 25.07.2024
Subjects
Bimetals
Calcium
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Summary:The dimeric β-diketiminato calcium hydride, [(BDI)CaH] (BDI = HC{(Me)CN-2,6- Pr C H } ), reacts with ZnMe to afford the bimetallic calcium zincate complex, [(BDI)Ca(μ-CH ) Zn(μ-H)] , which subsequently undergoes an intramolecular reaction to effect the formation of [(BDI)CaMe] , a notable omission from the homologous series of β-diketiminato alkylcalcium derivatives.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc02930e