Formation of 1,1,3-trimethyl-3-(4-methylphenyl)butyl hydroperoxide complex with tetrabutylammonium bromide

The interaction of 1,1,3-trimethyl-3-(4-methylphenyl)butyl peroxide with tetrabutylammonium bromide has been studied by means of 1 H NMR spectroscopy. The complex formation between the reacting species has been confirmed, its equilibrium constant being K = (3.01±0.09) L/mol at 294 K.

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 84; no. 1; pp. 16 - 17
Main Authors Turovskij, N. A., Raksha, E. V., Berestneva, Yu. V., Zubritskij, M. Yu
Format Journal Article
LanguageEnglish
Published Boston Springer US 2014
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Quaternary Ammonium Salt
Hydroperoxide
Ammonium Salt
Butyl Hydroperoxide
Tetrabutylammonium Bromide
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Summary:The interaction of 1,1,3-trimethyl-3-(4-methylphenyl)butyl peroxide with tetrabutylammonium bromide has been studied by means of 1 H NMR spectroscopy. The complex formation between the reacting species has been confirmed, its equilibrium constant being K = (3.01±0.09) L/mol at 294 K.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363214010046