Upconversion luminescence and optical thermometry in Er3+/Yb3+ co-doped CeO2 for space application

• Published in: Journal of alloys and compounds Vol. 774; pp. 418 - 424
• Main Authors: Bača, Ľuboš, Steiner, Hannes, Stelzer, Nils
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.02.2019
• Subjects: CeO2; Phosphors; Sensors; Space environment; Up-conversion luminescence; CeO2; Space environment; Up-conversion luminescence; Sensors; Phosphors
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2018.10.036

The Er3+, Yb3+ co-doped cerium(IV) oxide powders were synthesized by inverted co-precipitation method and calcined at 1000 °C and 1500 °C, respectively. The influence of dopant concentration and calcination temperatures on the luminescence efficiency under excitation with 980 nm laser light was systematically investigated. The maximum intensity of upconversion luminescence (UCL) was observed for CeO2:Yb5Er2 calcined at 1000 °C and CeO2:Yb2Er0.5 calcined at 1500 °C, respectively. Luminescence intensity ratios (LIR) in two Stark sub-levels in green and red regions were used for the determination of temperature sensitivity of CeO2:Yb2Er0.5 sintered at 1500 °C for 1 h. The sensitivity increased for the investigated coupled sub-levels from 0.001 K-1 to 0.003 K-1 (green region) and from 0.0011 K-1 to 0.0025 K-1 (red region). Thus Er3+/Yb3+ doped CeO2 phosphors with high temperature stability seem to be promising materials for low temperature optical measurement under vacuum. [Display omitted] •100 times enhancement of CeO2:Yb2Er0.5 luminescence with annealing temperature.•Best composition at 1000 °C: CeO2:Yb5Er2 - > dominant red colour.•Best composition at 1500 °C: CeO2:Yb2Er0.5 - > dominant green colour.•Ultra low temperature sensing based on luminescence intensity ratio (LIR).•CeO2:Yb2Er0.5 promising candidate as remote sensor for cryogenic temperatures.