Synthesis and structures of novel types of heteronuclear PtM (MAg, Sn or Pb) neutral or anionic organometallic complexes

Donor-acceptor Pt→Ag bonds formed by reactions between anionic platinum complexes and silver salts or complexes are the subject of this review. We discuss their structural features and the role played by the charge of the anions and by o-X…Ag interactions in the stability and spatial arrangement of...

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Bibliographic Details
Published inInorganica Chimica Acta Vol. 198; pp. 165 - 177
Main Authors Usón, R., Forniés, J.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.08.1992
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Summary:Donor-acceptor Pt→Ag bonds formed by reactions between anionic platinum complexes and silver salts or complexes are the subject of this review. We discuss their structural features and the role played by the charge of the anions and by o-X…Ag interactions in the stability and spatial arrangement of the resulting heteronuclear complexes. The extension of these studies to other M→M′ systems is briefly commented.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(00)92358-2