Aryloxy ‘biometal’ complexes as efficient catalysts for the synthesis of poly(butylene adipate terephthalate)

[Display omitted] A comparative study of catalytic activity of aryloxy complexes of Mg, Zn and Al in the synthesis of poly(butylene adipate terephthalate) demonstrated the preference of Al-based catalyst containing two bulky substituents in ortho-position of phenol ligand in terms of higher values o...

Full description

Saved in:
Bibliographic Details
Published inMendeleev communications Vol. 32; no. 3; pp. 351 - 353
Main Authors Nifant'ev, Ilya E., Bagrov, Vladimir V., Komarov, Pavel D., Ovchinnikova, Valeriya I., Ivchenko, Pavel V.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2022
Subjects
aluminum complexes
biodegradable polymers
biometals
esterification
PBAT
phenates
polycondensation
polyesters
PBAT
polycondensation
biometals
phenates
esterification
aluminum complexes
biodegradable polymers
polyesters
Online AccessGet full text

Cover

More Information
Summary:[Display omitted] A comparative study of catalytic activity of aryloxy complexes of Mg, Zn and Al in the synthesis of poly(butylene adipate terephthalate) demonstrated the preference of Al-based catalyst containing two bulky substituents in ortho-position of phenol ligand in terms of higher values of PBAT MW and lower yields of cyclic diester side product.
ISSN:0959-9436
DOI:10.1016/j.mencom.2022.05.020