A dye-loaded nonlinear metal-organic framework as self-calibrated optical thermometer

• Published in: Dyes and pigments Vol. 202; p. 110234
• Main Authors: Wan, Yating, Yu, Libing, Xia, Tifeng
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.06.2022
• Subjects: Dual-emitting; Dye; Metal-organic framework; SHG; Two-photon luminescence; Dye; Two-photon luminescence; Metal-organic framework; SHG; Dual-emitting
• ISSN: 0143-7208; 1873-3743
• DOI: 10.1016/j.dyepig.2022.110234

Facile and accurate temperature measurement is crucial in daily life, industrial applications, and scientific research. Here, we present a new strategy for physiological temperature sensing based on dual-emission from second harmonic generation (SHG) signal and two-photon luminescence in a dye-loaded nonlinear metal-organic framework (MOF) composite FIR-8⊃DMASM (DMASM = 4-[p-(dimethylamino)styryl]-1-methylpyridinium). Powder X-ray diffraction (PXRD), thermal gravimetric analysis (TGA), infrared absorption spectrum, single-photon luminescence, and the quantum yield indicate that encapsulation not only provides a two-photon luminescence center, but also improves the stability and quantum efficiency of dyes. Temperature-dependent spectroscopy shows that FIR-8⊃DMASM has excellent sensory performance in the physiological temperature region (20–60 °C) with high relative sensitivity of 1.36–2.98% oC−1. With good water stability and excellent biocompatibility, FIR-8⊃DMASM can be potentially applied in biological temperature sensing. A dye-loaded metal-organic framework FIR-8⊃DMASM shows excellent self-calibrated physiological temperature sensing performance with high relative sensitivity of 1.36–2.98% oC−1, good water stability, and excellent biocompatibility. [Display omitted] •Physiological thermometer based on dual-emitting MOF⊃dye composite has been realized.•Two signals for sensing are SHG and two-photon luminescence in MOF⊃dye composite.•FIR-8⊃DMASM exhibits high relative sensitivity, good repeatability, water stability and biocompatibility.