Efficient removal of ciprofloxacin and ofloxacin from aqueous solutions using a novel nano-scale adsorbent: Modeling, optimization, and characterization

• Published in: Chemosphere (Oxford) Vol. 354; p. 141640
• Main Authors: Farzinmanesh, Omid, Hosseini Sabzevari, Mina, Asghariganjeh, Mohammad R.
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.04.2024
• Subjects: Adsorption; Artificial neural network; Ciprofloxacin; Fluoroquinolone; Graphene oxide; Hydrogen-Ion Concentration; Isotherm; Kinetics; Ofloxacin; Optimization; Temperature; Thermodynamic; Thermodynamics; Water; Water Pollutants, Chemical - chemistry; Isotherm; Fluoroquinolone; Graphene oxide; Artificial neural network; Optimization; Thermodynamic
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2024.141640

In the fascinating realm of water purification, our study unveils the remarkable potential of a cutting-edge nano-scale adsorbent—combining graphene oxide (GO), chitosan (CS), and polydopamine (PDA)—in efficiently remove ciprofloxacin (CPF) and ofloxacin (OFL) from aqueous solutions. Our exploration delves deep into the adsorbent's character, utilizing a range of analytical techniques including SEM, RAMAN, FTIR, TGA, BET, XRD, and Zeta potential analyses provided insights into the adsorbent's properties. Modeling the adsorption process with Response Surface Methodology (RSM), Artificial Neural Network (ANN) and General Regression Neural Network (GRNN) indicated excellent predictions by GRNN, with RMSE = 0.0200 and 0.0166, MAE = 0.0082 and 0.0092, as well as AAD = 0.0002 and 0.0006, highlighting its modeling power. Optimization using genetic algorithm (GA) revealed maximum CPF removal efficiency of approximately 95.20% under pH = 6.3, sonication time = 9.0 min, adsorbent dosage = 2.10 g L⁻1, temperature = 45 °C and initial CPF concentration = 90.0 mg L⁻1. Similarly, OFL removal reached about 95.50% under pH = 6.30, sonication time = 8.0 min, adsorbent dosage = 2.0 g L⁻1, temperature = 45 °C and OFL concentration = 115.0 mg L⁻1. RSM optimization closely aligned with GA results. Pseudo-second-order (PSO) kinetic model and Langmuir isotherm model best fitted the experimental data for both antibiotics. Thermodynamic analysis indicated a favorable and spontaneous adsorption process for CPF and OFL. The study concludes that the proposed adsorbents show effectiveness in removing CPF and OFL at lower doses and shorter sonication times compared to various reported adsorbents. [Display omitted] •The highlights of the text are:•Synthesis of a novel nano-scale adsorbent incorporating GO, (CS), and PDA.•Comprehensive characterization of the as-prepared adsorbent using various techniques.•Demonstrated effectiveness of the adsorbent in removing CPF and OFL.•In-depth examination of adsorption isotherms, kinetics, thermodynamics, and reusability.