Reactions of a Niobium Nitride Complex Prepared from Dinitrogen: Synthesis of Imide and Ureate Complexes and Ammonia Formation (Eur. J. Inorg. Chem. 22-23/2013)

The back cover picture shows the molecular structure of the niobium ureate complex derived from N2 and CO2. The niobium nitride prepared from N2 activation by niobium hydride was alkylated with methyl iodide to afford the imide complex, which was converted to the ureate complex upon exposure to CO2...

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Published inEuropean journal of inorganic chemistry Vol. 2013; no. 22-23
Main Authors Akagi, Fumio, Suzuki, Shoui, Ishida, Yutaka, Hatanaka, Tsubasa, Matsuo, Tsukasa, Kawaguchi, Hiroyuki
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 06.08.2013
WILEY‐VCH Verlag
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Summary:The back cover picture shows the molecular structure of the niobium ureate complex derived from N2 and CO2. The niobium nitride prepared from N2 activation by niobium hydride was alkylated with methyl iodide to afford the imide complex, which was converted to the ureate complex upon exposure to CO2 in the presence of pyridine. Protonation of the nitride complex yielded ammonia along with niobium chloride, which could be recycled back to the niobium hydride. Details are discussed in the article by H. Kawaguchi et al. on p. 3930 ff.
Bibliography:istex:24001A5F4174C98A877C4050CA5FCAE1B97F3249
ArticleID:EJIC201390100
ark:/67375/WNG-Z218BC07-N
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.201390100