Synthesis of 3-Substituted Derivatives of 2,2,6,6-Tetramethylpiperidine-N- alkoxyamine Ethers: Novel Alkoxyamine Building Blocks

The Michael addition of 4-oxo-TMP-alkoxyamine-derived Schiff bases to acrylates provides a convenient way to obtain a variety of novel and versatile alkoxyamine building blocks.

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Bibliographic Details
Published inSynthesis (Stuttgart) no. 22; pp. 3873 - 3878
Main Authors Fischer, Walter, Basbas, Abdel-Ilah, Schoening, Kai-Uwe, Hauck, Stefan
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.11.2010
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CYCLOADDITION REACTIONS
ENANTIOSELECTIVE SYNTHESIS
radical reaction
piperidines
ENAMINES
POLYMERIZATION
peroxides
DYNAMIC KINETIC RESOLUTION
DESYMMETRIZATION
KETONES
N-alkoxyamines
TEMPO derivatives
RADICALS
INHIBITORS
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Summary:The Michael addition of 4-oxo-TMP-alkoxyamine-derived Schiff bases to acrylates provides a convenient way to obtain a variety of novel and versatile alkoxyamine building blocks.
ISSN:0039-7881
DOI:10.1055/s-0030-1258255