Synthesis of Isoquinolylselenocyanates and Quinolylselenocyanates via Electrophilic Selenocyanogen Cyclization Induced by Pseudohalogen (SeCN)2 Generated in situ

A strategy for the synthesis of isoquinolylselenocyanates and quinolylselenocyanates through electrophilic selenocyanogen cyclization has been developed. The feature of this reaction is that the sequential process was induced directly by generated in situ pseudohalogen (SeCN)2 generated in situ. Add...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 364; no. 1; pp. 187 - 192
Main Authors Wang, Jia, Wang, Yun‐Zhe, Liu, Yu‐Jie, Yan, Xin‐Xin, Yan, Yun‐Hui, Chao, Shu‐Jun, Shang, Xuefang, Ni, Tianjun, Zhou, Ping‐Xin
Format Journal Article
LanguageEnglish
Published Heidelberg Wiley Subscription Services, Inc 04.01.2022
Subjects
Electrophilic Selenocyanogen Cyclization
Functional groups
Generated in situ
Isoquinolylselenocyanates
Pseudohalogen (SeCN)2
Quinolylselenocyanates
Synthesis
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Summary:A strategy for the synthesis of isoquinolylselenocyanates and quinolylselenocyanates through electrophilic selenocyanogen cyclization has been developed. The feature of this reaction is that the sequential process was induced directly by generated in situ pseudohalogen (SeCN)2 generated in situ. Additionally, the obtained selenocyanates allowed functional group diversification, which could be potential intermediates for valuable compounds.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202101169