Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

Reaction of NO gas with sublimed layers of the Mn(II)TPP (TPP =meso-tetraphenylporphyrinato2-) at low temperature leads to nitric oxide disproportionation. UV-Vis and FTIR spectroscopy with isotopically substituted nitrogen oxides revealed formation of the unstable species identified as trans-Mn(III...

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Published inChemical communications (Cambridge, England) no. 13; pp. 1488 - 1489
Main Authors Martirosyan, Garik G, Azizyan, Arsen S, Kurtikyan, Tigran S, Ford, Peter C
Format Journal Article
LanguageEnglish
Published England 07.07.2004
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Summary:Reaction of NO gas with sublimed layers of the Mn(II)TPP (TPP =meso-tetraphenylporphyrinato2-) at low temperature leads to nitric oxide disproportionation. UV-Vis and FTIR spectroscopy with isotopically substituted nitrogen oxides revealed formation of the unstable species identified as trans-Mn(III)(TPP)(NO)(ONO).
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/b404491f