Facile synthesis of (E)-beta-nitroolefinic alkoxyamines via silver-catalyzed decarboxylative nitroaminoxylation of phenylpropiolic acids

A novel silver-catalyzed decarboxylative nitroaminoxylation reaction of phenylpropiolic acids is described, leading to (E)-beta-nitro-olefinic alkoxyamines. The catalyst loading could be decreased to as low as 1 mol%, whilst still showing good efficiency.

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Bibliographic Details
Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 17; no. 5; pp. 2723 - 2726
Main Authors Yan, Hong, Mao, Jincheng, Rong, Guangwei, Liu, Defu, Zheng, Yang, He, Yue
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2015
Subjects
Chemistry
Chemistry, Multidisciplinary
Green & Sustainable Science & Technology
Physical Sciences
Science & Technology
Science & Technology - Other Topics
TRANSITION
ALKENES
(BUONO)-BU-T
ARYL DIAZONIUM SALTS
OLEFINS
ALKYNES
STEREOSELECTIVE NITRATION
C-H
AEROBIC OXYNITRATION
CARBOXYLIC-ACIDS
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Summary:A novel silver-catalyzed decarboxylative nitroaminoxylation reaction of phenylpropiolic acids is described, leading to (E)-beta-nitro-olefinic alkoxyamines. The catalyst loading could be decreased to as low as 1 mol%, whilst still showing good efficiency.
ISSN:1463-9262
1463-9270
DOI:10.1039/c5gc00302d