Microporous metal–organic layer built from pentanuclear tetrahedral units: gas sorption and magnetism

Presented herein is a porous layer motif 1 built from pentanuclear tetrahedral Ni-clusters with accessible metal centers. Activated 1 exhibits a high selectivity of 19.8 at 273 K and 1 bar for the separation of CO 2 over CH 4 . Magnetic measurement shows the overall antiferromagnetic coupling betwee...

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Bibliographic Details
Published inNew journal of chemistry Vol. 38; no. 11; pp. 5272 - 5275
Main Authors Tan, Yan-Xi, Zhang, Ying, He, Yan-Ping, Zheng, Yan-Jun
Format Journal Article
LanguageEnglish
Published 01.01.2014
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Summary:Presented herein is a porous layer motif 1 built from pentanuclear tetrahedral Ni-clusters with accessible metal centers. Activated 1 exhibits a high selectivity of 19.8 at 273 K and 1 bar for the separation of CO 2 over CH 4 . Magnetic measurement shows the overall antiferromagnetic coupling between Ni( ii ) ions for 1 .
ISSN:1144-0546
1369-9261
DOI:10.1039/C4NJ00517A