Reaction of Benzylidene Chlorides with О-Methyl Diethylphosphinothioate

О -Methyl diethylphosphinothioate reacts with benzylidene chlorides to form arenecarbthioaldehyde trimers and diethylphosphinoyl chloride. This result suggests that the reaction involves initial attack of the thione sulfur atom of the phosphinothioyl group on the methine carbon atom of the gem-dichl...

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Bibliographic Details
Published inRussian journal of general chemistry Vol. 88; no. 8; pp. 1754 - 1756
Main Authors Gazizov, M. B., Valieva, G. D., Ivanova, S. Yu, Karimova, R. F., Ismagilov, R. K., Khairullin, R. A.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.08.2018
Springer Nature B.V
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chlorides
Dichlorides
Letters to the Editor
Trimers
benzylidene chlorides
dechlorodiethylphosphinothioylation
methyl diethylphosphinothioate
arenecarbthioaldehyde trimer
dechlorodiethylphosphinothioyloxylation
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Summary:О -Methyl diethylphosphinothioate reacts with benzylidene chlorides to form arenecarbthioaldehyde trimers and diethylphosphinoyl chloride. This result suggests that the reaction involves initial attack of the thione sulfur atom of the phosphinothioyl group on the methine carbon atom of the gem-dichloride.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363218080327