The Millimeterwave Spectrum and Structure of Chloroacetylene

The ground state rotational spectra of HCC 35Cl, HCC 37Cl, and their two [ 13C ]-, and [D]-isotopomers have been measured up to 500 GHz. From the set of rotational constants obtained, r 0, r s, r ϵ, I , and r ρ m structures have been determined.

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Bibliographic Details
Published inJournal of molecular spectroscopy Vol. 158; no. 2; pp. 357 - 362
Main Authors Leguennec, M., Wlodarczak, G., Demaison, J., Burger, H., Polanz, O.
Format Journal Article
LanguageEnglish
Published San Diego, CA Elsevier Inc 1993
Elsevier
Subjects
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Rotation, vibration and vibration-rotation constants
Millimetric wave
Isotope effect
Acetylenic compound
Molecular structure
Chlorocarbon
Rotational transition
Rotational constant
Molecular constant
Experimental study
Rotational analysis
Organic compounds
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Summary:The ground state rotational spectra of HCC 35Cl, HCC 37Cl, and their two [ 13C ]-, and [D]-isotopomers have been measured up to 500 GHz. From the set of rotational constants obtained, r 0, r s, r ϵ, I , and r ρ m structures have been determined.
ISSN:0022-2852
1096-083X
DOI:10.1006/jmsp.1993.1080