Solvent effects on piezochromism of transition metal complexes

We report solvent effects on the piezochromic behaviour of wavelengths of maximum absorption for metal-to-ligand charge-transfer (m.l.c.t.) bands of several molybdenum-diimine-carbonyl and titanium or vanadium-cyclopentadienyl or ethylmaltolate-thiocyanate complexes. These and previously published d...

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Published inTransition metal chemistry (Weinheim) Vol. 23; no. 5; p. 615
Main Authors Burgess, John, Maguire, Sarah, Mcgranaghan, Andrea, Parsons, Simon A, Nowicka, Beata, Samotus, Alina
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Nature B.V 01.10.1998
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Summary:We report solvent effects on the piezochromic behaviour of wavelengths of maximum absorption for metal-to-ligand charge-transfer (m.l.c.t.) bands of several molybdenum-diimine-carbonyl and titanium or vanadium-cyclopentadienyl or ethylmaltolate-thiocyanate complexes. These and previously published data are collated in an attempt to establish a pattern for solvent effects on piezochromism of m.l.c.t. bands. Strategies for the design of compounds and complexes for use in establishing a clear pattern for such effects are outlined.[PUBLICATION ABSTRACT]
ISSN:0340-4285
1572-901X
DOI:10.1023/A:1006934217418