Ferroelectric and piezoelectric properties of Ca2+ and Sn4+ substituted BaTiO3 lead-free electroceramics on the emphasis of phase coexistence
The Ba1-xCaxTi1-ySnyO3 (abbreviated as BCxTSy, x = 0.01, y = 0.01; x = 0.03, y = 0.015; x = 0.05, y = 0.02; and x = 0.07, y = 0.025 mol.) electroceramics were synthesized by solid-state reaction method and investigated their structural, dielectric, ferroelectric and piezoelectric properties. Rietvel...
Saved in:
Published in | Solid state communications Vol. 306; p. 113797 |
---|---|
Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
01.02.2020
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | The Ba1-xCaxTi1-ySnyO3 (abbreviated as BCxTSy, x = 0.01, y = 0.01; x = 0.03, y = 0.015; x = 0.05, y = 0.02; and x = 0.07, y = 0.025 mol.) electroceramics were synthesized by solid-state reaction method and investigated their structural, dielectric, ferroelectric and piezoelectric properties. Rietveld refinement of X-ray diffraction data for the composition x = 0.03, y = 0.015 reveals the phase co-existence of two non-centrosymmetric orthorhombic (Amm2) (7.71%) + tetragonal (P4mm) (92.29%) lattice symmetries near room temperature which is also evidenced by temperature-dependent Raman and dielectric studies. All compositions reveal the dense microstructure having relative density ~92%–96% and average grain size ~10.7–22.5 μm. The phase diagram based on dielectric study suggests that the composition x = 0.03, y = 0.015 reveals T(R–O) ~ − 60 °C, T(O-T) ~ 19 °C and TC ~ 126 °C with Pr = 11.80 μC/cm2, Ec = 3.5 kV/cm, Pmax = 21.92 μC/cm2, d33* = 505.5 pm/V, d33 = 287 pC/N and electrostrictive coefficient (Q33) = 0.036 m4/C2 properties which could be useful for developing the piezoelectric AC devices. Here, we have achieved the phase-coexistence of two non-centrosymmetric lattice symmetries near room temperature to invoke the reliable ferroelectric and piezoelectric properties and discussed the results with the structure-property-composition relation.
•Ba0.97Ca0.03Ti0.985Sn0.015O3 reveal the phase co-existence of orthorhombic and tetragonal lattices near room temperature.•Temperature-dependent Raman and dielectric studies also supports the phase co-existence.•Relatively higher Curie temperature (Tc) ~ 126 oC is observed for Ba0.97Ca0.03Ti0.985Sn0.015O3 with d33 = 287 pC/N.•Ferroelectric and piezoelectric response of BCxTSy ceramics seems to be improved in the vicinity of phase co-existence. |
---|---|
ISSN: | 0038-1098 1879-2766 |
DOI: | 10.1016/j.ssc.2019.113797 |