Influence of surface treatment on properties of Cocos nucifera L. Var typica fiber reinforced polymer composites

• Published in: Journal of applied polymer science Vol. 140; no. 3
• Main Authors: Brailson Mansingh, Bright, Binoj, Joseph Selvi, Siengchin, Suchart, Sanjay, Mavinkere Rangappa
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 15.01.2023; Wiley Subscription Services, Inc
• Subjects: agro‐waste; Benzoyl peroxide; Biodegradability; Chemical treatment; Fiber composites; Fiber reinforced polymers; Fibers; Flexural strength; Hydrophobicity; Impact strength; Materials science; mechanical characteristics; Mechanical properties; moisture behavior; partial biodegradability; Polyester resins; Polymer matrix composites; Polymers; Potassium; Potassium permanganate; Sodium hydroxide; Stearic acid; surface modification; Surface treatment; sustainable reinforcement; Tensile strength; Thermal stability; Thermomechanical properties; Water absorption
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.53345

Natural fibers are a powerful competitor in the polymer composite market due to their availability, sustainability, obtainability, cost, and biodegradability. The surface of natural fibers was changed to increase mechanical qualities, hydrophobicity, and bonding with polymer matrix. This study exposes the influence of several surface treatments of coconut tree peduncle fibers (CTPFs) on the thermomechanical and water absorption properties of CTPF‐reinforced polymer composites. The CTPFs were treated with sodium hydroxide, benzoyl peroxide, potassium permanganate and stearic acid at a constant 40 wt% and individually reinforced in an unsaturated polyester resin matrix containing 60 wt% CTPFs. Chemically treated CTPFs improved reinforcement‐matrix adhesion and enhanced composite mechanical characteristics. In addition, the scanning electron microscope fractographical study of stressed composite specimens shows improved reinforcement‐matrix bonding. Moreover, the treated CTPFs have a higher cellulose wt%, which improves the composites crystalline nature, hydrophobicity and thermal stability. The potassium permanganate treated CTPF composite's maximum tensile strength of 128 MPa, flexural strength of 119 MPa, impact strength of 9.9 J/cm2, hardness value of 99 HRRW and thermal stability up to 193°C make them appropriate for lightweight mobility and structural applications.