Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio]tetrathiafulvalene and related materials

The synthesis of four novel organosulfur donors carrying two or more hydroxymethyl groups are described. TTF nuclei are fused to 1,4-dithiepine and/or 1,4-dithiine rings and in two cases both outer rings carry functionality capable of introducing hydrogen bonding; for the two chiral organosulfur don...

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Bibliographic Details
Published inPerkin 1 : an international journal of organic and bio-organic chemistry no. 4; pp. 407 - 414
Main Authors Ozturk, T, Saygili, N, Ozkara, S, Pilkington, M, Rice, CR, Tranter, DA, Turksoy, F, Wallis, JD
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2001
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
PI-DONOR
ELECTROCHEMISTRY
TETRATHIAFULVALENES
TTF
SYSTEMS
BETA''-(ET)SF5RSO3 R
SULFUR
BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE
DERIVATIVES
PRECURSORS
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Summary:The synthesis of four novel organosulfur donors carrying two or more hydroxymethyl groups are described. TTF nuclei are fused to 1,4-dithiepine and/or 1,4-dithiine rings and in two cases both outer rings carry functionality capable of introducing hydrogen bonding; for the two chiral organosulfur donor molecules both racemic and enantiopure forms are prepared.
ISSN:1472-7781
DOI:10.1039/b007660k