Highly efficient C-C coupling reactions using metallated benzylphosphine complexes of palladium

Phosphapalladacyclic complexes synthesised from ortho-bromobenzylphosphine ligands are effective catalysts for carbon-carbon bond forming reactions, exhibiting activity that compares with, and in several examples exceeds, that of existing systems.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 8; pp. 779 - 780
Main Authors Gibson, S, Foster, DF, Eastham, GR, Tooze, RP, Cole-Hamilton, DJ
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2001
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
HALIDES
ARYL
HECK REACTION
PALLADACYCLES
CATALYSTS
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Summary:Phosphapalladacyclic complexes synthesised from ortho-bromobenzylphosphine ligands are effective catalysts for carbon-carbon bond forming reactions, exhibiting activity that compares with, and in several examples exceeds, that of existing systems.
ISSN:1359-7345
1364-548X
DOI:10.1039/b100328n