Influence of Nd3+ substitution on thermoelectric power of Zn-Mg ferrite system
Polycrystalline ferrites, ZnxMg1−xFe2−yNdyO4 (x = 0.00, 0.20, 0.40, 0.60, 0.80 and 1.00;y = 0.00, 0.05 and 0.10) were prepared by standard ceramic method. X-ray diffraction study of these compositions revealed the formation of single phase spinels. Seebeck coefficient was obtained from thermo emf me...
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Published in | Bulletin of materials science Vol. 23; no. 2; pp. 87 - 90 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Bangalore
Springer Nature B.V
01.04.2000
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Subjects | |
Online Access | Get full text |
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Summary: | Polycrystalline ferrites, ZnxMg1−xFe2−yNdyO4 (x = 0.00, 0.20, 0.40, 0.60, 0.80 and 1.00;y = 0.00, 0.05 and 0.10) were prepared by standard ceramic method. X-ray diffraction study of these compositions revealed the formation of single phase spinels. Seebeck coefficient was obtained from thermo emf measurement by keeping constant temperature difference of 10 K across the pellet. The values of Seebeck coefficient were found to be negative showing majority charge carriers ofn-type, suggesting the mechanism of conduction to be predominantly by electron hopping. The substitution of Nd3+ ion, which perhaps resides at the B-site, resulting in a decrease in the Seebeck coefficient. This decrease was assigned to the decrease of population of Fe3+ ion at the B-site. The activation energies calculated both from mobility plots and from dc resistivity plots were found comparable. The Fermi energy,EF(0), which was estimated by intrapolation ofEF-T curves toT = 0 K, was found less than the activation energy. This difference was attributed to electron hopping energy. |
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ISSN: | 0250-4707 0973-7669 |
DOI: | 10.1007/BF02706547 |