Catalytic effect of alkali carbonates on CO2 gasification of Pingshuo coal

• Published in: Mining science and technology (China) Vol. 21; no. 4; pp. 587 - 590
• Main Authors: Meng, Lili, Wang, Meijun, Yang, Huimin, Ying, Hongyan, Chang, Liping
• Format: Journal Article
• Language: English
• Published: Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China 01.07.2011
• Subjects: Na2C03; 二氧化碳; 催化效应; 催化效果; 催化气化; 动力学分析; 煤炭; 碱金属碳酸盐; Gasification; Catalysis; Coal; Alkali carbonates; TGA
• ISSN: 1674-5264; 2212-6066
• DOI: 10.1016/j.mstc.2011.01.001

Na2CO3, Li2CO3, and K2CO3 were used as additives to Pingshuo （PS） coal that was subsequently gasified under a CO2 stream. The catalytic gasification of coal samples by CO2 in the presence single or mixed alkali carbonates was investigated by thermogravimetric analysis. The experimental results indicate that the catalytic effect of Li2CO3 is significantly larger than that of Na2CO3 or K2CO3. The catalytic effect of the mixed, bi-metal carbonate containing Li2C03 and Na2C03, or Li2CO3, and K2C03, is related to the compo- sition of the catalyst and the proportion of the two components. The bi-metal carbonates having a mole ratio of 9：1 （lri：x） has the largest catalytic effect for PS coal gasification. A synergistic effect between Li and K, or Na, carbonate appears at temperatures greater than 1300 K. An un-reacted shrinking core model is suitable for kinetic analysis of catalytic gasification of coal samples in the presence of alkali carbonates. It is inappropriate, however, to evaluate the catalytic effect only by the activation energy obtained from the kinetic calculations.