In situ creation of multi-metallic species inside porous silicate materials with tunable catalytic properties

Porous metal silicate (PMS) material PMS-11, consisting of uniformly distributed multi-metallic species inside the pores, is synthesized by using a discrete multi-metal coordination complex as the template, demonstrating high catalytic activity and selectivity in hydrogenation of halogenated nitrobe...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 57; no. 50; pp. 6185 - 6188
Main Authors Liu, Yang-Yang, Zhan, Guo-Peng, Wu, Chuan-De
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 22.06.2021
Royal Society of Chemistry
Subjects
Catalytic activity
Chemistry
Chemistry, Multidisciplinary
Coordination compounds
Lewis acid
Nickel
Nitrobenzene
Physical Sciences
Porous materials
Science & Technology
Selectivity
Transition metals
NANOPARTICLES
N-DOPED CARBON
SELECTIVE HYDROGENATION
CHLORONITROBENZENE
EFFICIENT
COMPLEXES
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Summary:Porous metal silicate (PMS) material PMS-11, consisting of uniformly distributed multi-metallic species inside the pores, is synthesized by using a discrete multi-metal coordination complex as the template, demonstrating high catalytic activity and selectivity in hydrogenation of halogenated nitrobenzenes by synergistically activating different reactant molecules via Ni and Co transition metal centers, while Gd-III Lewis acid sites play a role in tuning the catalytic properties.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc01797g