Syntheses and characterisation of some triphenylcyanoborate complexes of rhodium(II) and palladium(II)

The triphenylcyanoborate (N-bonded) complexes {η 5-(C 5Me 5)Rh(S S)-NCBPh 3} (S S− = −S 2PMe 2, −S 2PPh 2, −S 2CNMe 2), {η 6-(C 6H 6)Ru(S 2PPh 2)-NCBPh 3} and [Pd(S 2 CNEt 2)(PMe 2Ph)(NCBPh 3) have been synthesised and characterised by both spectroscopic and X-ray structural methods.

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 135; no. 2; pp. C50 - C52
Main Authors Cornock, M.C., Robertson, D.R., Stephenson, T.A., Jones, C.L., Milburn, G.H.W., Sawyer, L.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 02.08.1977
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Summary:The triphenylcyanoborate (N-bonded) complexes {η 5-(C 5Me 5)Rh(S S)-NCBPh 3} (S S− = −S 2PMe 2, −S 2PPh 2, −S 2CNMe 2), {η 6-(C 6H 6)Ru(S 2PPh 2)-NCBPh 3} and [Pd(S 2 CNEt 2)(PMe 2Ph)(NCBPh 3) have been synthesised and characterised by both spectroscopic and X-ray structural methods.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)80870-0