Syntheses and characterisation of some triphenylcyanoborate complexes of rhodium(II) and palladium(II)
The triphenylcyanoborate (N-bonded) complexes {η 5-(C 5Me 5)Rh(S S)-NCBPh 3} (S S− = −S 2PMe 2, −S 2PPh 2, −S 2CNMe 2), {η 6-(C 6H 6)Ru(S 2PPh 2)-NCBPh 3} and [Pd(S 2 CNEt 2)(PMe 2Ph)(NCBPh 3) have been synthesised and characterised by both spectroscopic and X-ray structural methods.
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Published in | Journal of organometallic chemistry Vol. 135; no. 2; pp. C50 - C52 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
02.08.1977
|
Online Access | Get full text |
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Summary: | The triphenylcyanoborate (N-bonded) complexes {η
5-(C
5Me
5)Rh(S
S)-NCBPh
3} (S
S− =
−S
2PMe
2,
−S
2PPh
2,
−S
2CNMe
2), {η
6-(C
6H
6)Ru(S
2PPh
2)-NCBPh
3} and [Pd(S
2 CNEt
2)(PMe
2Ph)(NCBPh
3) have been synthesised and characterised by both spectroscopic and X-ray structural methods. |
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ISSN: | 0022-328X 1872-8561 |
DOI: | 10.1016/S0022-328X(00)80870-0 |