Engineered hybrid iron‐cobalt metal oxide nanoparticles for effective adsorption of malachite green dye

• Published in: Journal of chemical technology and biotechnology (1986) Vol. 99; no. 12; pp. 2553 - 2568
• Main Authors: Hussain, Nasira, Shafaat, Shanza, Sarfraz, Ambreen, Usman, Muhammad, Khan, Muhammad Saqib, Khan, Asad Muhammad, Khan, Rafaqat Ali, Amin, Bilal Ahmad Zafar, Bilal, Muhammad, Shaikh, Ahson Jabbar
• Format: Journal Article
• Language: English
• Published: Chichester, UK John Wiley & Sons, Ltd 01.12.2024; Wiley Subscription Services, Inc
• Subjects: Adsorption; Aqueous solutions; Cobalt; Color removal; Dyes; Ferric oxide; Ferromagnetism; hybrid metal oxide; hydrodynamic size; Iron; Malachite green; malachite green dye; Metal oxides; Multilayers; nanoparticle engineering; Nanoparticles; zeta potential
• ISSN: 0268-2575; 1097-4660
• DOI: 10.1002/jctb.7737

BACKGROUND Hybrid iron and cobalt metal oxide nanoparticles are well known; however, are not optimized in terms of size and stability. We engineered these hybrid nanoparticles using the co‐precipitation method and characterized them by various techniques, which are then used for the effective adsorption and removal of malachite green (MG) dye. RESULTS The ideal conditions for synthesis are determined to be 50:50 ratio of Fe2O3 and CoO, pH of 11, temperature range of 40 °C–60 °C, and reactant addition time of 20 min. These hybrid nanoadsorbents effectively eliminated MG dye from aqueous solutions. Factors such as initial MG dye concentration, pH of the medium, contact time, temperature, and nanoadsorbent dose were optimized for the MG removal to achieve a maximum removal efficiency of 96.9%. Non‐linear fitting of data indicates that both Langmuir and Freundlich models provided the best fit, suggesting the presence of both monolayer and multilayer adsorption of MG on hybrid nanoparticles. The kinetics of MG dye removal are better controlled by the intraparticle diffusion (IPD) phenomenon. The adsorption of MG onto the hybrid nanoparticles was confirmed to be endothermic, with negative ΔG and positive ΔH values. The optimized synthetic conditions also positively impacted the hybrid nanoparticles which enhanced the adsorption and exhibited ferromagnetic behavior as compared to the superparamagnetic behavior reported in the literature, making them significantly important for dye removal applications. CONCLUSION These findings demonstrate the potential of optimized hybrid nanoparticles as effective nanoadsorbents for dye removal applications, with implications for further applications in photocatalysis and sensing. © 2024 Society of Chemical Industry (SCI).