First example of peroxosolvate of iodine-containing organic molecule

[Display omitted] Six new bispidine-based bis-amides containing residues of haloacetic acids were synthesized and characterized by X-ray crystallography. The dissolution of iodine-containing compound in concentrated hydrogen peroxide afforded bispidine peroxosolvate, in which the peroxide molecules...

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Published inMendeleev communications Vol. 31; no. 3; pp. 352 - 355
Main Authors Churakov, Andrei V., Medved’ko, Aleksei V., Prikhodchenko, Petr V., Krut’ko, Dmitry P., Vatsadze, Sergey Z.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2021
Subjects
3,7-diazabicyclo[3.3.1]nonane
conformation analysis
hydrogen peroxide
organoiodine compounds
peroxosolvates
X-ray diffraction study
α-halo carbonyl compounds
conformation analysis
3,7-diazabicyclo[3.3.1]nonane
X-ray diffraction study
hydrogen peroxide
α-halo carbonyl compounds
peroxosolvates
organoiodine compounds
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Summary:[Display omitted] Six new bispidine-based bis-amides containing residues of haloacetic acids were synthesized and characterized by X-ray crystallography. The dissolution of iodine-containing compound in concentrated hydrogen peroxide afforded bispidine peroxosolvate, in which the peroxide molecules participated in two donor hydrogen bonds with carbonyl oxygen atoms of the distinct adjacent organic molecules thus forming cyclic motifs in crystals. This structure is a first example of peroxosolvate of iodine-containing organic molecule.
ISSN:0959-9436
DOI:10.1016/j.mencom.2021.04.023