Metal ion initiated halogenation reaction of N-haloamines

The metal ion catalyzed chlorination of 1-chlorobutane, 1-chlorohexane, methyl-pentanoate, and methyl-heptanoate by protonated N-chloroamines proceeds by a free radical chain mechanism and the chain carrying species was shown not to be a chlorine atom, but an amino radical cation.

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Bibliographic Details
Published inCanadian journal of chemistry Vol. 48; no. 4; pp. 544 - 545
Main Authors Minisci, F, Gardini, G. P, Bertini, F
Format Journal Article
LanguageEnglish
Published Ottawa, Canada NRC Research Press 15.02.1970
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Summary:The metal ion catalyzed chlorination of 1-chlorobutane, 1-chlorohexane, methyl-pentanoate, and methyl-heptanoate by protonated N-chloroamines proceeds by a free radical chain mechanism and the chain carrying species was shown not to be a chlorine atom, but an amino radical cation.
ISSN:0008-4042
1480-3291
DOI:10.1139/v70-090