Non-stoichiometric uranyl fluoride complexes with pyridine

Complexes of the type UO 2F 2·( x) pyridine, where x = 0.71 and 1.65, were prepared by the interaction of liquid pyridine on solid UO 2F 2 under similar conditions with the only reaction variable being temperature. These materials have been characterized by chemical reactivity, thermogravimetric ana...

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Bibliographic Details
Published inJournal of inorganic & nuclear chemistry Vol. 41; no. 7; pp. 991 - 995
Main Author Maas, E.T.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 1979
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Summary:Complexes of the type UO 2F 2·( x) pyridine, where x = 0.71 and 1.65, were prepared by the interaction of liquid pyridine on solid UO 2F 2 under similar conditions with the only reaction variable being temperature. These materials have been characterized by chemical reactivity, thermogravimetric analysis, IR spectral analysis and powder X-ray diffractometry. While the exact structure of these materials remains unknown, the possibility of their existence as intercalation compounds is explored.
ISSN:0022-1902
1878-1225
DOI:10.1016/0022-1902(79)80075-5