Rhodium perfluorobutyramide (Rh 2(pfm) 4): a synthetically useful catalyst for olefin aziridinations

[Display omitted] Rhodium perfluorobutyramide (Rh 2(pfm) 4) has been shown to catalyze the conversion of olefins to trichloroethoxysulfonyl, nosyl, and tosyl aziridines. Advantages of this aziridination procedure include the microwave-assisted preparation of the catalyst and the practical use of the...

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Bibliographic Details
Published inTetrahedron letters Vol. 46; no. 23; pp. 4031 - 4034
Main Authors Keaney, Gregg F., Wood, John L.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 06.06.2005
Subjects
Aziridination
Kalihinane diterpenoids
Microwave
Nosyl
Rhodium perfluorobutyramide
Tosyl
Trichloroethoxysulfonyl
Kalihinane diterpenoids
Aziridination
Microwave
Tosyl
Nosyl
Trichloroethoxysulfonyl
Rhodium perfluorobutyramide
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Summary:[Display omitted] Rhodium perfluorobutyramide (Rh 2(pfm) 4) has been shown to catalyze the conversion of olefins to trichloroethoxysulfonyl, nosyl, and tosyl aziridines. Advantages of this aziridination procedure include the microwave-assisted preparation of the catalyst and the practical use of the alkene substrate as the limiting reagent.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2005.04.027