Rydberg energies of some three-electron ions

The energies of the Rydberg states of the three-electron atom and several three-electron ions have been calculated. The effects of using successively improved core functions are noted. The results are compared to self-consistent field energies where these are available. A spin-free formulation of th...

Full description

Saved in:
Bibliographic Details
Published inJournal of molecular spectroscopy Vol. 19; no. 1; pp. 73 - 77
Main Authors Hempel, J.C., Browne, J.C., Matsen, F.A.
Format Journal Article
LanguageEnglish
Published Elsevier Inc 1966
Online AccessGet full text

Cover

More Information
Summary:The energies of the Rydberg states of the three-electron atom and several three-electron ions have been calculated. The effects of using successively improved core functions are noted. The results are compared to self-consistent field energies where these are available. A spin-free formulation of the perturbation problem was employed.
ISSN:0022-2852
1096-083X
DOI:10.1016/0022-2852(66)90230-X