Efficient Pb(II) removal from contaminated soils by recyclable, robust lignosulfonate/polyacrylamide double-network hydrogels embedded with Fe2O3 via one-pot synthesis

• Published in: Journal of hazardous materials Vol. 479; p. 135712
• Main Authors: Hu, Tian, Zhang, Mingkai, Wei, Xiujiao, Xu, Zhaoxin, Li, Deyun, Deng, Jianbin, Li, Yongtao, Zhang, Yulong, Lin, Xueming, Wang, Jinjin
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.11.2024
• Subjects: Adsorption; Contaminated soil; Double-network hydrogel; Pb removal; Remediation; Pb removal; Double-network hydrogel; Contaminated soil; Remediation; Adsorption
• ISSN: 0304-3894; 1873-3336; 1873-3336
• DOI: 10.1016/j.jhazmat.2024.135712

Soil heavy metal removal strategies are increasingly valued for effectively reducing contamination and preventing secondary pollution. In this work, a double network hydrogel (Fe2O3@LH), consisting of lignosulfonate (LS) and polyacrylamide with embedded Fe2O3 nanoparticles, was synthesized successfully via a one-pot method and subsequently applied to adsorb lead (Pb) from contaminated soil. Incorporating Fe2O3 into the hydrogel enhances the adsorption capacity of Fe2O3@LH for Pb(II). The Fe2O3@LH hydrogel demonstrates a maximum Pb(II) adsorption capacity of 143.11 mg g–1, with Pb(II) removal mechanisms involving electrostatic adsorption, cation exchange, precipitation reactions, and the formation of coordination complexes, achieving a 22.3 % maximum removal efficiency in soil cultivation experiments. Additionally, the application of Fe2O3@LH markedly reduces the concentrations of cadmium (Cd) and arsenic (As) in the soil, meanwhile enhances the levels of total nitrogen (TN), soil organic matter (SOM), and cation exchange capacity (CEC) by 23.1 %, 10.6 %, and 16.9 %, respectively. Following 90 days of continuous application in the soil, the recovery rate of Fe2O3@LH remains above 75 %. The toxicity assay using zebrafish larvae indicates that Fe2O3@LH demonstrates good biosafety. This study demonstrates the considerable potential of Fe2O3@LH hydrogel for practical application in reducing Pb(II) levels in contaminated soil. [Display omitted] •A novel, recyclable, robust double-network hydrogel (Fe2O3@LH) synthesized in one-pot synthesis for soil Pb removal.•The embedding of Fe2O3 NPs enhances both the adsorption capacity for Pb2+ and the mechanical properties of the hydrogel.•Fe2O3@LH has a Pb2+ adsorption capacity of 143.11 mg g–1, primarily involving chemisorption and monolayer adsorption.•Application of Fe2O3@LH hydrogel reduces the Pb content in contaminated soil by 22.3 %.•Fe2O3@LH also reduces As and Cd in soil while concurrently enhancing soil properties indicators such as TN, SOM, and CEC.